Lee, Cayo, Alina J. Cook, Jonathan E. Elisabeth, Nathan C. Friede, Glenn M. Sammis, and Nicholas D. Ball. “The Emerging Applications of Sulfur (VI) Fluorides in Catalysis.” ACS catalysis 11 (2021): 6578-6589.
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The past decade has witnessed remarkable growth of catalytic transformations in organic sulfur(VI) fluoride chemistry. This Perspective concentrates exclusively on foundational examples that utilize catalytic strategies to synthesize and react S(VI) fluorides. Key mechanistic studies that aim to provide insight toward future catalytic systems are emphasized.